JOURNAL ARTICLE

Supramolecular p-n-heterojunctions by co-self-organization of oligo(p-phenylene vinylene) and perylene bisimide dyes

Frank Würthner, Zhijian Chen, Freek J M Hoeben, Peter Osswald, Chang-Cheng You, Pascal Jonkheijm, Jeroen V Herrikhuyzen, Albertus P H J Schenning, Paul P A M van der Schoot, E W Meijer, Edwin H A Beckers, Stefan C J Meskers, René A J Janssen
Journal of the American Chemical Society 2004 September 1, 126 (34): 10611-8
15327319
Comparative studies on hydrogen-bonded versus covalently linked donor-acceptor-donor dye arrays obtained from oligo(p-phenylene vinylene)s (OPVs) as donor and bay-substituted perylene bisimides (PERYs) as acceptor dyes are presented. Both systems form well-ordered J-type aggregates in methylcyclohexane, but only hydrogen-bonded arrays afford hierarchically assembled chiral OPV-PERY dye superstructures consisting of left-handed helical pi-pi co-aggregates (CD spectroscopy) of the two dyes that further assemble into right-handed nanometer-scale supercoils in the solid state (AFM study). In the case of hydrogen-bonded arrays, the stability of the aggregates in solution increases with increasing conjugation length of the OPV unit. The well-defined co-aggregated dyes presented here exhibit photoinduced electron transfer on subpicosecond time scale, and thus, these supramolecular entities might serve as valuable nanoscopic functional units.

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