keyword
https://read.qxmd.com/read/38687206/fabrication-of-a-sustainable-superhydrophobic-surface-of-ag-nps-sa-on-copper-alloy-for-corrosion-resistance-photocatalysis-and-simulated-distribution-of-ag-atoms
#61
JOURNAL ARTICLE
Noor Hassan, Zeeshan Ajmal, Sun Liang Heng, Khaled Fahmi Fawy, Sajid Mahmood, Fazila Mushtaq, Munirah D Albaqami, Saikh Mohammad, Raqiqa Tur Rasool, Ghulam Abbas Ashraf
Artificial superhydrophobic surfaces that do not absorb water, like the lotus leaf, show tremendous promise in numerous applications. However, superhydrophobic surfaces are rarely used because of their low stability and endurance. A stable organic superhydrophobic surface (SHS) composed of novel morphology Ag-nanoparticles (NPs) has been fabricated on a copper alloy via etching, immersion, spraying, and annealing treatment, along with a static water contact angle (WCA) of 158 ± 1° and sliding angle (SA) less than 2°...
April 30, 2024: Analyst
https://read.qxmd.com/read/38687195/tartaric-acid-cross-linking-polyvinyl-alcohol-as-degradable-separators-for-rechargeable-lithium-ion-batteries
#62
JOURNAL ARTICLE
Huimin Yuan, Kun Liu, Wen Luo, Zhiqiang Wang, Chunliu Yan, Jing Hu, Xinyang Wang, Guiyu Liu, Zhenghe Xu, Zhouguang Lu
The escalating focus on environmental concerns and the swift advancement of eco-friendly biodegradable batteries raises a pressing demand for enhanced material design in the battery field. The traditional polypropylene (PP) that is monopolistically utilized in the commercial LIBs is hard to recycle. In this work, we prepare a novel water degradable separators via the cross-linking of polyvinyl alcohol (PVA) and dibasic acid (tartaric acid, TA). Through the integration of non-solvent liquid-phase separation, we successfully produced a thermally stable PVA-TA membrane with tunable thickness and a high level of porosity...
April 30, 2024: ChemSusChem
https://read.qxmd.com/read/38685172/metabolites-are-overlooked-in-environmental-risk-assessments-and-monitoring-of-pharmaceuticals-the-case-study-of-pantoprazole
#63
JOURNAL ARTICLE
Finnian Freeling, Dominic Armbruster, Karsten Nödler, Uwe Kunkel, Marco Scheurer, Jan Koschorreck, Thomas A Ternes
The proton-pump inhibitor pantoprazole (PPZ) is one of the most consumed pharmaceuticals worldwide. Despite its high usage, reported PPZ concentrations in environmental water samples are comparatively low, which can be explained by the extensive metabolism of PPZ in the human body. Since most previous studies did not consider human PPZ metabolites it can be assumed that the current environmental exposure associated with the application of PPZ is substantially underestimated. In our study, 4'-O-demethyl-PPZ sulfide (M1) was identified as the predominant PPZ metabolite by analyzing urine of a PPZ consumer as well as the influent and effluent of a wastewater treatment plant (WWTP) using liquid chromatography coupled to high resolution mass spectrometry (LC-HRMS)...
April 9, 2024: Water Research
https://read.qxmd.com/read/38684695/al-ce-co-doped-batio-3-nanofibers-as-a-high-performance-bifunctional-electrochemical-supercapacitor-and-water-splitting-electrocatalyst
#64
JOURNAL ARTICLE
Fatemeh Zakeri, Abbas Javid, Yasin Orooji, Arezou Fazli, Amirreza Khataee, Alireza Khataee
Supercapacitors and water splitting cells have recently played a key role in offering green energy through converting renewable sources into electricity. Perovskite-type electrocatalysts such as BaTiO3 , have been well-known for their ability to efficiently split water and serve as supercapacitors due to their high electrocatalytic activity. In this study, BaTiO3 , Al-doped BaTiO3 , Ce-doped BaTiO3 , and Al-Ce co-doped BaTiO3 nanofibers were fabricated via a two-step hydrothermal method, which were then characterized and compared for their electrocatalytic performance...
April 29, 2024: Scientific Reports
https://read.qxmd.com/read/38684671/all-natural-2d-nanofluidics-as-highly-efficient-osmotic-energy-generators
#65
JOURNAL ARTICLE
Jiadong Tang, Yun Wang, Hongyang Yang, Qianqian Zhang, Ce Wang, Leyuan Li, Zilong Zheng, Yuhong Jin, Hao Wang, Yifan Gu, Tieyong Zuo
Two-dimensional nanofluidics based on naturally abundant clay are good candidates for harvesting osmotic energy between the sea and river from the perspective of commercialization and environmental sustainability. However, clay-based nanofluidics outputting long-term considerable osmotic power remains extremely challenging to achieve due to the lack of surface charge and mechanical strength. Here, a two-dimensional all-natural nanofluidic (2D-NNF) is developed as a robust and highly efficient osmotic energy generator based on an interlocking configuration of stacked montmorillonite nanosheets (from natural clay) and their intercalated cellulose nanofibers (from natural wood)...
April 29, 2024: Nature Communications
https://read.qxmd.com/read/38683214/evaluating-the-effect-of-npo-status-on-mucosal-coating-during-double-contrast-barium-esophagrams
#66
JOURNAL ARTICLE
Hamad M Muhammad, Ahmed M Amer, Elainea N Smith, Jessica G Zarzour, David Summerlin, Desiree E Morgan, Samuel J Galgano
INTRODUCTION: Current guidelines for double contrast barium esophagography studies (BAS) suggest that patients should be nil per os (NPO) prior to completing BAS for optimal esophageal coating, although the time required varies between practices and institutions. It is believed that consumption of food or water disrupts the ability for thick barium contrast to properly coat the esophageal mucosa. Exams that are rescheduled for this reason can lead to delays in care, without substantial evidence that NPO status truly affects esophageal mucosal coating for these exams with current barium mixtures...
April 29, 2024: Abdominal Radiology
https://read.qxmd.com/read/38682723/fast-structural-dynamics-in-concentrated-hcl-solutions-from-proton-hopping-to-the-bulk-viscosity
#67
JOURNAL ARTICLE
Laura Kacenauskaite, Max Moncada Cohen, Stephen J Van Wyck, Michael D Fayer
Concentrated acid solutions, particularly HCl, have been studied extensively to examine the proton hopping and infrared spectral signatures of hydronium ions. Much less attention has been given to the structural dynamics of concentrated HCl solutions. Here, we apply optical heterodyne detected-optical Kerr effect (OHD-OKE) measurements to examine HCl concentration-dependent dynamics from moderate (0.8 m) to very high (15.5 m) concentrations and compare the results to the dynamics of NaCl solutions, as Na+ is similar in size to the hydronium cation...
April 29, 2024: Journal of the American Chemical Society
https://read.qxmd.com/read/38682647/a-simple-fast-and-inexpensive-approach-to-quantify-low-concentrations-of-iron-in-biodiesel-by-voltammetry-after-extraction-induced-by-microemulsion-breaking
#68
JOURNAL ARTICLE
Cristian H Krause, Alexandre B Schneider, Leandro Kolling, Lauren T T Oliveira, Márcia M da Silva
An alternative approach to assay iron (Fe) in biodiesel by differential pulse adsorptive cathodic stripping voltammetry (DPAdCSV) is presented herein. The sample treatment involved a simple, rapid, but effective extraction of Fe from biodiesel into an aqueous phase after microemulsion (ME) breaking. Then, Fe was determined as the complex Fe(III)-PAN (1-(2-pyridylazo)-2-naphthol) on a glassy carbon electrode (GCE) in the presence of bismuth (Bi(III)). The extraction induced by microemulsion breaking (EIMB) was achieved by adding 0...
April 29, 2024: Analytical Methods: Advancing Methods and Applications
https://read.qxmd.com/read/38681576/impact-of-8-week-cold-and-warm-water-swimming-training-combined-with-cinnamon-consumption-on-serum-metrnl-hdac5-and-insulin-resistance-levels-in-diabetic-male-rats
#69
JOURNAL ARTICLE
Seyed Morteza Tayebi, Saleh Motaghinasab, Rasoul Eslami, Somayeh Ahmadabadi, Aref Basereh, Iman Jamhiri
OBJECTIVE: Numerous studies have reported the beneficial effects of exercise and the use of herbal supplements in improving type 2 diabetes and insulin resistance. However, there are still many unanswered questions about the effects of cold and hot water, exercise, and herbal supplements on meteorine-like protein (METRNL), which is considered one of the key factors influencing insulin resistance improvement in this condition. Hence, the current study aimed to address these knowledge gaps and investigate the effects of 8 weeks of warm and cold-water swimming exercise with cinnamon consumption on serum levels of METRNL, histone deacetylase-5 (HDAC5), and insulin resistance in diabetic male rats...
April 30, 2024: Heliyon
https://read.qxmd.com/read/38681286/impact-of-lifestyle-and-dietary-habits-on-the-prevalence-of-acne-vulgaris-a-cross-sectional-study-from-saudi-arabia
#70
JOURNAL ARTICLE
Ghadah Khormi, Najat Aldubayyan, Manar Hakami, Sarah Daghriri, Sultan Aqeel
Background Acne vulgaris is a prevalent dermatological condition worldwide, with its impact significantly influenced by various genetic, environmental, and lifestyle factors. Despite its global prevalence, data on acne's prevalence and risk factors in Saudi Arabia remain sparse. This study aims to fill this gap by examining the prevalence of acne vulgaris and identifying associated lifestyle and environmental risk factors within the Saudi population. Methodology Employing a cross-sectional survey-based design, this study collected data from a representative sample of the Saudi population aged 18 years and older...
March 2024: Curēus
https://read.qxmd.com/read/38681148/efficacy-and-safety-of-the-water-pressure-method-for-endoscopic-submucosal-dissection-in-superficial-pharyngeal-cancer
#71
JOURNAL ARTICLE
Noriko Matsuura, Motohiko Kato, Kentaro Iwata, Kurato Miyazaki, Teppei Masunaga, Yoko Kubosawa, Mari Mizutani, Yukie Hayashi, Motoki Sasaki, Tomohisa Sujino, Kaoru Takabayashi, Teppei Akimoto, Yusaku Takatori, Atsushi Nakayama, Mariko Sekimizu, Hiroyuki Ozawa, Naohisa Yahagi
Background and study aims Superficial pharyngeal cancers can be cured with transoral surgery (TOS), which preserves organ function and quality of life. Pharyngeal endoscopic submucosal dissection (ESD) is challenging to perform because of limited maneuverability and complex anatomical features. The water pressure method (WPM) is useful for natural traction techniques during ESD and is potentially useful for pharyngeal ESD. This study aimed to investigate the short-term outcomes of WPM-ESD for pharyngeal lesions...
April 2024: Endoscopy International Open
https://read.qxmd.com/read/38681089/enhancing-drug-delivery-efficacy-through-bilayer-coating-of-zirconium-based-metal-organic-frameworks-sustained-release-and-improved-chemical-stability-and-cellular-uptake-for-cancer-therapy
#72
JOURNAL ARTICLE
Xiewen Liu, Joanna Obacz, Giulia Emanuelli, Joseph E Chambers, Susana Abreu, Xu Chen, Emily Linnane, Joshua P Mehta, Andrew E H Wheatley, Stefan J Marciniak, David Fairen-Jimenez
The development of nanoparticle (NP)-based drug carriers has presented an exciting opportunity to address challenges in oncology. Among the 100,000 available possibilities, zirconium-based metal-organic frameworks (MOFs) have emerged as promising candidates in biomedical applications. Zr-MOFs can be easily synthesized as small-size NPs compatible with intravenous injection, whereas the ease of decorating their external surfaces with functional groups allows for targeted treatment. Despite these benefits, Zr-MOFs suffer degradation and aggregation in real, in vivo conditions, whereas the loaded drugs will suffer the burst effect-i...
April 23, 2024: Chemistry of Materials: a Publication of the American Chemical Society
https://read.qxmd.com/read/38678975/analysis-of-carcass-traits-meat-quality-amino-acid-and-fatty-acid-profiles-between-different-duck-lines
#73
JOURNAL ARTICLE
Fan Li, Yinglin Lu, Zongliang He, Debing Yu, Jing Zhou, Heng Cao, Xingyu Zhang, Hongjie Ji, Kunpeng Lv, Minli Yu
To investigate the effect of genetic selection on meat quality in ducks, twenty of each fast growth ducks (LCA) and slow growth ducks (LCC) selected from F6 generation of Cherry Valley ducks (♂) x Liancheng white ducks (♀) were analyzed for carcass characteristics, meat quality (physicochemical and textural characteristics), amino acid and fatty acid profiles at 7 wk. Results showed that live body weight, slaughter weight, eviscerated yield and abdominal fat percentage of LCA were significantly higher than those in LCC ducks (P < 0...
April 20, 2024: Poultry Science
https://read.qxmd.com/read/38678928/a-pump-free-paper-pdms-hybrid-microfluidic-chip-for-bacteria-enrichment-and-fast-detection
#74
JOURNAL ARTICLE
Zhengshan Zhu, Zilan Lv, Li Wang, Haolan Tan, Yi Xu, Shunbo Li, Li Chen
Developing portable and sensitive biosensors for bacteria detection is highly demanded due to their association with environmental and food safety. Paper-based microfluidic chip is the suitable candidate for constructing pump-free biosensor since paper is hydrophilic, low-cost and easy to use. However, the contradiction between sensitivity and small sample volume seriously affects the application of paper-based chip for bacteria detection. Here, a new microfluidic biosensor, combining large PDMS reservoir for sample storage, hydrophilic paper substrate for pump-free water transport, coated microspheres for bacteria capture and super absorbent resin for water absorption, is designed for the detection of bacteria in aqueous samples...
April 26, 2024: Talanta
https://read.qxmd.com/read/38678843/nitrogen-doped-carbon-dots-as-fluorescent-probes-for-sensitive-and-selective-determination-of-fe-3
#75
JOURNAL ARTICLE
Yulin Ma, Linhan Mao, Congcong Cui, Yong Hu, Zhaoxia Chen, Yuan Zhan, Yuhong Zhang
At present, the contamination of water resources by heavy metal ions has posed a significant threat to human survival. Therefore, it is particularly critical to develop low-cost, easy-to-use, and highly efficient heavy metal detection technologies. In this work, a fast and cost-effective fluorescent probe for nitrogen-doped carbon dots (N-CDs) was prepared using one-step hydrothermal method with citric acid (CA) as carbon source, and melamine as nitrogen source. The structural and optical characterizations of the resulting N-CDs were investigated in details...
April 24, 2024: Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy
https://read.qxmd.com/read/38678314/size-specific-dose-estimation-in-pediatric-ct-preliminary-study-and-conversion-factors
#76
JOURNAL ARTICLE
Jian Zhang, Xiaojun Zhang
The objective of this paper is to compare the differences between volumetric CT dose index (CTDIVOL) and size-specific dose estimate (SSDEWED) based on water equivalent diameter (WED) in radiation dose measurement, and explore a new method for fast calculation of SSDEWED. The imaging data of 1238 cases of head, 1152 cases of chest and 976 cases of abdominopelvic were analyzed retrospectively, and they were divided into five age groups: ≤ 0.5, 0.5 ~ ≤ 1, 1 ~ ≤ 5, 5 ~ ≤ 10 and 10 ~ ≤ 15 years according to age...
April 27, 2024: Radiation Protection Dosimetry
https://read.qxmd.com/read/38677413/quantification-of-microbial-community-assembly-processes-during-degradation-on-diverse-plastispheres-based-on-physicochemical-characters-and-phylogenetic-bin-based-null-model-analysis
#77
JOURNAL ARTICLE
Daiki Yokoyama, Yuri Tsuboi, Hideki Abe, Ritsuko Nagahata, Hideo Konno, Masaru Yoshida, Jun Kikuchi
To understand the differences in degradation processes depending on the chemical properties of polymers, it is necessary to both quantify the microbiome composition and evaluate the process of microbial turnover (i.e., community assembly processes) in a variety of polymer materials. In this study, using a phylogenetic bin-based null model analysis (i.e., iCAMP), we evaluated community assembly processes from original estuary water to 37 types of polymers, which provide overwhelmingly diverse niches for microbes, in 14-day incubation experiments...
April 25, 2024: Science of the Total Environment
https://read.qxmd.com/read/38676092/simultaneous-electrochemical-detection-of-cu-2-and-zn-2-in-pig-farm-wastewater
#78
JOURNAL ARTICLE
Jia-Xin Du, Yang-Hao Ma, Said Nawab, Yang-Chun Yong
In recent years, the rapid development of pig farming has led to a large quantity of heavy metal-polluted wastewater. Thus, it was desirable to develop a simple heavy metal detection method for fast monitoring of the wastewater from the pig farms. Therefore, there was an urgent need to develop a simple method for rapidly detecting heavy metal ions in pig farm wastewater. Herein, a simple electrochemical method for simultaneous detection of Cu2+ and Zn2+ was developed and applied to pig farm wastewater. With a glassy carbon electrode and anodic stripping voltammetry, simultaneous detection of Cu2+ and Zn2+ in water was achieved without the need for complicated electrode modification...
April 12, 2024: Sensors
https://read.qxmd.com/read/38675625/hierarchically-structured-graphene-aerogel-supported-nickel-cobalt-oxide-nanowires-as-an-efficient-electrocatalyst-for-oxygen-evolution-reaction
#79
JOURNAL ARTICLE
Donglei Guo, Jiaqi Xu, Guilong Liu, Xu Yu
The rational design of a heterostructure electrocatalyst is an attractive strategy to produce hydrogen energy by electrochemical water splitting. Herein, we have constructed hierarchically structured architectures by immobilizing nickel-cobalt oxide nanowires on/beneath the surface of reduced graphene aerogels (NiCoO2 /rGAs) through solvent-thermal and activation treatments. The morphological structure of NiCoO2 /rGAs was characterized by microscopic analysis, and the porous structure not only accelerates the electrolyte ion diffusion but also prevents the agglomeration of NiCoO2 nanowires, which is favorable to expose the large surface area and active sites...
April 16, 2024: Molecules: a Journal of Synthetic Chemistry and Natural Product Chemistry
https://read.qxmd.com/read/38675517/core-shell-cos-2-mos-2-with-hollow-heterostructure-as-an-efficient-electrocatalyst-for-boosting-oxygen-evolution-reaction
#80
JOURNAL ARTICLE
Donglei Guo, Jiaqi Xu, Guilong Liu, Xu Yu
It is imperative to develop an efficient catalyst to reduce the energy barrier of electrochemical water decomposition. In this study, a well-designed electrocatalyst featuring a core-shell structure was synthesized with cobalt sulfides as the core and molybdenum disulfide nanosheets as the shell. The core-shell structure can prevent the agglomeration of MoS2 , expose more active sites, and facilitate electrolyte ion diffusion. A CoS2 /MoS2 heterostructure is formed between CoS2 and MoS2 through the chemical interaction, and the surface chemistry is adjusted...
April 9, 2024: Molecules: a Journal of Synthetic Chemistry and Natural Product Chemistry
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