Annika Sickinger, Maxime Grasser, Bruno Baguenard, Amina Bensalah-Ledoux, Laure Guy, Anh Thy Bui, Yannick Guyot, Vincent Dorcet, Fabrice Pointillart, Olivier Cador, Stéphan Guy, Olivier Maury, Boris Le Guennic, François Riobé
Chiral, enantiopure Yb(III) complexes exhibit circularly polarized luminescence (CPL) in the near infrared (NIR) wavelength region. This CPL is quantified by the dissymmetry factor ( g lum ). The excited state 2 F5/2 consists of six m J ' states degenerated in three Stark levels, due to the crystal-field splitting (CFS), which are populated in accordance with the Boltzmann distribution. Consequently, room temperature CPL spectra are the sum of various - either positive or negative - contributions, that are practically impossible to quantify...
May 21, 2024: Physical Chemistry Chemical Physics: PCCP