photocatalyst

CO2 -to-high value-added chemicals via a photocatalytic route is of interest but strangled by the low efficiency. Herein, a novel Fe-TiO2-x /TiO2 S-scheme homojunction was designed and constructed by using a facile surface modification approach whereby oxygen vacancy (OV) and Fe introducing on the TiO2 nanorod surface. The as-synthesized Fe-TiO2-x /TiO2 S-scheme homojunction exhibits positive properties on promoting photocatalytic CO2 reduction: i) the nanorod structure provides numerous active sites and a radical charge transfer path; ii) the doped Fe and OV not only synergistically enhance light utilization but also promote CO2 adsorption; iii) the Fe-TiO2-x /TiO2 S-scheme homojunction benefits photoexcited charge separation and retains stronger redox capacity...

Layered double hydroxide (LDH) is an applicable material that can be modified in various ways. Modifications using natural extracts fulfill the principles of "green chemistry." The preparation of butterfly pea flower extract (BPE)-modified NiAl LDH was completed using the calcination and restacking method. The characteristics of the prepared composites were identified through analysis of functional groups, crystal phase, bandgap energy, surface area and surface morphology. Fourier transform-infrared (FT-IR) characterization revealed that the active group of the catalyst is -OH except for NiAl layered double oxide (LDO), which has the metal oxide-like functional groups...

Utilizing solar energy for photocatalytic CO2 reduction is an attractive research field because of its convenience, safety, and practicality. The selection of an appropriate photocatalyst is the key to achieve efficient CO2 reduction. Herein, we report the synthesis of TiO2 /CuPc heterojunctions by compositing CuPc with TiO2 microspheres via a hydroxyl-induced self-assembly process. The experimental investigations demonstrated that the optimal TiO2 /0.5CuPc photocatalyst exhibited a significantly enhanced CO2 photoreduction rate up to 32...

Carbon nitride (C3 N4 ) has gained considerable attention and has been regarded as an ideal candidate for photocatalytic hydrogen evolution. However, its photocatalytic efficiency is still unsatisfactory due to the rapid recombination rate of photo-generated carriers and restricted surface area with few active sites. Herein, we successfully synthesized a single-atom Pt cocatalyst-loaded photocatalyst by utilizing the anchoring effect of carbon dots (CDs) on C3 N4 . The introduction of CDs onto the porous C3 N4 matrix can greatly enhance the specific surface area of C3 N4 to provide more surface-active sites, increase light absorption capabilities, as well as improve the charge separation efficiency...

The design and synthesis of organic photocatalysts remain a great challenge due to their strict structural constraints. However, this could be mitigated by achieving structural flexibility by constructing permanent porosity into the materials. Conjugated microporous polymers (CMPs) are an emerging class of porous materials with an amorphous, three-dimensional network structure, which makes it possible to integrate the elaborate functional groups to enhance photocatalytic performance. Here, we report the synthesis of a novel CMP, named TAPFc-TFPPy-CMP, constructed by 1,1'3,3'-tetra(4-aminophenyl)ferrocene (TAPFc) and 1,3,6,8-tetrakis(4-formylphenyl)pyrene (TFPPy) monomers...

A novel photocatalytic nanomaterial, Ho2 YSbO7 , was successfully synthesized for the first time using the solvothermal synthesis technique. In addition, a Ho2 YSbO7 /Bi2 MoO6 heterojunction photocatalyst (HBHP) was prepared via the hydrothermal fabrication technique. Extensive characterizations of the synthesized samples were conducted using various instruments, such as an X-ray diffractometer, a Fourier transform infrared spectrometer, a Raman spectrometer, a UV-visible spectrophotometer, an X-ray photoelectron spectrometer, and a transmission electron microscope, as well as X-ray energy dispersive spectroscopy, photoluminescence spectroscopy, a photocurrent test, electrochemical impedance spectroscopy, ultraviolet photoelectron spectroscopy, and electron paramagnetic resonance...

Access to clean drinking water is a basic requirement, and eliminating pollutants from wastewater is important for saving water ecosystems. The porous structure and surface characteristics of metal-organic frameworks (MOFs) can function as a perfect scaffold for removing toxic compounds from wastewater. Porphyrins are promising building blocks for constructing MOFs. Porphyrin-based metal-organic frameworks (P-MOFs) have been fabricated using porphyrin ligands, metal clusters, or ions. These materials can harvest light from a wide region of the solar spectrum, and their framework morphology and physicochemical properties can be controlled by changing their peripheral subunits or metal ions...

The recent rise in textile dye wastewater discharge into the environment has detrimental effects on living organisms and human health. The present study reports a facile approach to green-synthesized AuNPs employing sesbania gum for catalytic and photocatalytic degradation of organic pollutants. The obtained AuNPs were characterized by various techniques such as UV-vis, FT-IR, SEM, TEM, AFM, zeta potential, LC-MS, and XPS. The XRD patterns revealed a highly crystalline and face-centered cubic structure. XPS and EDX analysis defined the chemical composition and product purity of SBG-AuNPs...

Theoretical examination based on first principle computation has been conducted for van der Waals heterostructure (vdwHS) GaAlS2/HfS2 including structural, optoelectronic and photocatalytic characteristics. From the adhesion energy calculation, the AB configuration of GaAlS2/HfS2 vdwHS is the most stable. A type-II GaAlS2/HfS2 vdwHS is a dynamically and thermally stable structure. The band edge position, projected band, and projected charge densities verify the type-II alignment of GaAlS2/HfS2 vdwHS. For GaAlS2/HfS2, GaAlS2 is acting as a donor and HfS2 is acting as an acceptor ensured by the charge density difference plot...

Photocatalysis is a green and environmentally friendly method for degrading dangerous and nonbiodegradable pollutants. In this study, a sequence of metal-free triazine-based electronic donor-acceptor (D-A) conjugated polymers Tr-X (X = Th, BT, BTh) were prepared by D-A configuration regulation between triazine (Tr) and monomers containing N and S, such as thiophene (Th), bithiophene (BTh) and benzothiadiazole (BT) units, for the photocatalytic degradation of bisphenol A (BPA) and benzene contaminants in water under visible light...

[5,15-Bis(pentafluorophenyl)-10,20-diphenylporphinato]zinc(II) ( 1 ), a metalloporphyrin derivative that was recently reported as an efficient photocatalyst driven by blue LEDs by our group, was found to catalyze a red-light-promoted (630 nm LEDs) radical cascade reaction of N -3-arylpropionyloxyphthalimides with radicophiles including electron-deficient alkenes and alkynes, providing access to a range of functionalized tetralin and dialin derivatives. The radical cascade reaction catalyzed by 1 took place via an oxidative quenching cycle in DMSO, where no sacrificial electron donor was required, uncovering a unique solvent effect capable of promoting the porphyrin catalysis...

Currently, microplastics (MPs) are considered as emerging aqueous pollutants. However, existing methods for the separation and treatment of MPs from an aquatic environment are limited by their low efficiency. Advanced oxidation processes (AOPs) are novel techniques that employ photo-induced electron/hole pairs to generate active radicals for MP mineralization. Thus, in this study, a photocatalyst, i.e., Ag+ ion-doped TiO2 , heterojunctioned with carbon nanotubes (CNT), was synthesized to study the degradation of typical MPs such as polystyrene (PS) under solar irradiation...

In this study, we have synthesized nanostructured titanium dioxide (TiO2 ) photocatalysts under different configurations, viz. , anatase, rutile and anatase/rutile heterophase ( E g = 3.14-2.96 eV) through a sol-gel route. The photocatalytic performance of the heterophase samples was better than that of their phase-pure counterparts. Photocatalytic performance was maximum for sample T12H (50% rutile) with a rate constant, k = (7.38 ± 1.48) × 10-2 min-1 . This is ca. 47% greater than that estimated via an extrapolation method using the values for phase pure samples indicating synergistic effects...

Formaldehyde (CH2 O) emerges as a significant air pollutant, necessitating effective strategies for its oxidation to mitigate adverse impacts on human health and the environment. Among various technologies, the photooxidation of CH2 O stands out owing to its affordability, safety, and effectiveness. Nitrogen-rich crystalline triazine-based organic frameworks (CTFs) exhibit considerable potential in this domain. Nevertheless, the weak and unstable CH2 O adsorption hinders the overall oxidation efficiency of CTF...

Solar-driven CO2 reduction into value-added C2+ chemical fuels, such as C2 H4 , is promising in meeting the carbon-neutral future, yet the performance is usually hindered by the high energy barrier of the C─C coupling process. Here, an efficient and stabilized Cu(I) single atoms-modified W18 O49 nanowires (Cu1 /W18 O49 ) photocatalyst with asymmetric Cu─W dual sites is reported for selective photocatalytic CO2 reduction to C2 H4 . The interconversion between W(V) and W(VI) in W18 O49 ensures the stability of Cu(I) during the photocatalytic process...

Disposable bamboo chopsticks (DBCs) are difficult to recycle, which inevitably cause secondary pollution. Based on energy and environmental issues, we propose a facile strategy to fabricate floatable photocatalyst (fPC) coated onto DBCs, which can be flexibly used in water purification. The photocatalyst of titania and titanium carbide on bamboo (TiO2 /TiC@b) was successfully constructed from TiC-Ti powders and DBCs using a coating technique followed heat treatment in carbon powder, and the fPC exhibited excellent photocatalytic activity under visible light irradation...

The designed synthesis of an S-scheme heterojunction has possessed a great potential for improving photocatalytic wastewater treatment by demostrating increased the photoredox capacity and improved the charge separation efficiency. Here, we introduce the fabrication of a heterojunction-based photocatalyst comprising bismuth oxychloride (BiOCl) and bismuth-based halide perovskite (BHP) nanosheets, derived from metal-organic frameworks (MOFs). Our composite photocatalyst is synthesized through a one-pot solvothermal strategy, where a halogenation process is applied to a bismuth-based metal-organic framework (CAU-17) as the precursor for bismuth sourcing...

This study explores the utilization of semiconductor-based photocatalysts for environmental remediation through photocatalytic degradation, harnessing solar energy for effective treatment. The primary focus is on the application of photocatalytic technology for the degradation of 2-chlorophenol and methylene blue, critical pollutants requiring remediation. The research involves the synthesis of binary AgAlO2 /g-C3 N4 nanocomposites through an exchange ion method, subsequent calcination, and sonication. This process enhances the transfer of photogenerated electrons from AgAlO2 to g-C3 N4 , resulting in a significantly increased reductive electron charge on the surface of g-C3 N4 ...

In this study, a novel Z-scheme heterojunction on bismuth vanadium/cadmium sulfide (BiVO4 /0.6CdS) was developed and evaluated for simultaneous photocatalytic removal of combined tetracycline (TC) and hexavalent chromium Cr(Ⅵ) pollution under visible light. Based on the analysis of intermediate products and theoretical calculation, the property of the intermediate products of TC degradation and the effect of built-in electric field (IEF) of composite materials on photo-generated carrier separation were illustrated...

Utilization of renewable energies for catalytically generating value-added chemicals is highly desirable in this era of rising energy demands and climate change impacts. Artificial photosynthetic systems or photocatalysts utilize light to convert abundant CO2 , H2 O, and O2 to fuels, such as carbohydrates and hydrogen, thus converting light energy to storable chemical resources. The emergence of intense X-ray pulses from synchrotrons, ultrafast X-ray pulses from X-ray free electron lasers, and table-top laser-driven sources over the past decades opens new frontiers in deciphering photoinduced catalytic reaction mechanisms on the multiple temporal and spatial scales...