Xing Huang, Yang Li, Shuai Fu, Chao Ma, Yang Lu, Mingchao Wang, Peng Zhang, Ze Li, Feng He, Chuanhui Huang, Zhongquan Liao, Ye Zou, Shengqiang Zhou, Manfred Helm, Petko St Petkov, Hai I Wang, Mischa Bonn, Jian Li, Wei Xu, Renhao Dong, Xinliang Feng
Conjugated coordination polymers (c-CPs) are unique organic-inorganic hybrid semiconductors with intrinsically high electrical conductivity and excellent charge carrier mobility. However, it remains a challenge in tailoring electronic structures, due to the lack of clear guidelines. Here, we develop a strategy wherein controlling the redox state of hydroquinone/benzoquinone (HQ/BQ) ligands allows for the modulation of the electronic structure of c-CPs while maintaining the structural topology...
March 15, 2024: Angewandte Chemie