Supaphorn Thammakan, Nobuto Yoshinari, Marie Tsuchikawa, Apinpus Rujiwatra, Takumi Konno
Immersing single crystals of (Δ)4 -K6 [Ir4 Zn4 O(l-cysteinate)12 ]· n H2 O (K6 [ 1 Ir ]· n H2 O) bearing 12 free carboxylate groups, which was newly prepared from Δ-H3 [Ir(l-cysteinate)3 ], ZnBr2 , ZnO, and KOH, in an aqueous solution of lanthanide(III) acetate produced Ln2 [ 1 Ir ]· n H2 O ( 2 Ln ; Ln = LaIII , CeIII , PrIII , and NdIII ) and Ln0.33 [Ln4 (OH)4 (OAc)3 (H2 O)7 ][ 1 Ir ]· n H2 O ( 3 Ln ; Ln = SmIII , EuIII , GdIII , TbIII , DyIII , ErIII , HoIII , TmIII , YbIII , and LuIII ) in a single-crystal-to-single-crystal transformation manner...
March 23, 2024: Inorganic Chemistry