OER nanoparticles

Heterogeneous catalysts have attracted extensive attention among various emerging catalysts for their exceptional oxygen evolution reaction (OER) capabilities, outperforming their single-component counterparts. Nonetheless, the synthesis of heterogeneous materials with predictable, precise, and facile control remains a formidable challenge. Herein, a novel strategy involving the decoration of catalysts with CeO2 is introduced to concurrently engineer heterogeneous interfaces and adjust phase composition, thereby enhancing OER performance...

Phase transformation offers an alternative strategy for the synthesis of nanomaterials with unconventional phases, allowing us to further explore their unique properties and promising applications. Herein, we first observed the amorphization of Pt nanoparticles on the RuO2 surface by in situ scanning transmission electron microscopy. Density functional theory calculations demonstrate the low energy barrier and thermodynamic driving force for Pt atoms transferring from the Pt cluster to the RuO2 surface to form amorphous Pt...

The reality of long-term rechargeable and high-performance zinc-air batteries relies majorly on cost-effective and eminent bifunctional electrocatalysts, which can perform both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER). Herein, we demonstrate a new approach for the synthesis of in-situ-grown layered double hydroxide of iron and cobalt over a cobalt nanoparticle-enriched nitrogen-doped carbon frame (CoL 2:1) by a simple coprecipitation reaction with facile scale-up and explore its electrocatalytic ORR and OER activity for an electrically rechargeable zinc-air battery...

Bimetallic phosphides are considered as promising electrocatalysts for zinc-air batteries toward oxygen evolution reaction (OER) and oxygen reduction reaction (ORR). To address the semi-conductor inherent low electronic conductivity and catalytic activity, a polymetal-chelated strategy is employed to in situ fabricate bimetallic nanophosphides within carbon matrix anchoring by chemical bonding. The employment of biomolecule polydopamine (PDA) efficiently anchors various transition metal ions due to its strong chelating capability via inherent functional groups...

In oxygen electrocatalysis, how to rationally design low-cost catalysts with reasonable structure and long-term stability is a crucial issue. Here, an in-situ growth strategy is used to construct a shaped structure encapsulating a uniformly-dispersed Co/Co3 Fe7 heterojunction in nitrogen-doped carbon nanotubes (Co/Co3 Fe7 @NCNTs). Hollow CoFe layered-double-hydroxide prisms act as sacrifices for in-situ growth of Co/Co3 Fe7 nanoparticles, which also catalyze the growth of bamboo-like NCNTs. Tubular structure not only accelerates the charge transfer through the interactions between Co and Co3 Fe7 , but also limits the aggregation of the particles, thereby promoting the 4e- oxygen reduction/evolution reactions (ORR/OER) kinetics and stabilizing the bifunctional activity...

Covalent organic frameworks (COFs) and metal-organic frameworks (MOFs) have attracted growing attention in electrochemical energy storage and conversion systems (e.g., Zn-air batteries, ZABs) owing to their structural tunability, ordered porosity and high specific surface area. In this work, for the first time, the three-dimensional (3D) highly open catalyst (CNFs/CoZn-MOF@COF) possessing hierarchical porous structure and high-density active sites of uniform cobalt (Co) nanoparticles and metal-Nx (M-Nx , M = Co and Zn) is demonstrated, which is fabricated using electrospinning technique in combination with MOF/COF hybridization strategy and direct pyrolysis...

Traditional noble metal oxide, such as RuO2 , is considered a benchmark catalyst for acidic oxygen evolution reaction (OER). However, its practical application is limited due to sluggish activity and severe electrochemical corrosion. In this study, we synthesize Ru-Fe nanoparticles loading on carbon felt (RuFe@CF) via an ultrafast joule-heating method as an active and durable OER catalyst in acidic conditions. Remarkably low overpotentials of 188 and 269 mV are achieved at 10 and 100 mA cm-2 , respectively, with a robust stability up to 620 hours at 10 mA cm-2 ...

The lattice oxygen mechanism (LOM) offers an efficient reaction pathway for oxygen evolution reactions (OERs) in energy storage and conversion systems. Owing to the involvement of active lattice oxygen that enhances electrochemical activity in this approach, addressing the structural and electrochemical stabilities of LOM materials is crucial. Therefore, it is important to devise effective strategies for activating lattice oxygen in such materials while minimizing material deformations and ion elution. Herein, a heterostructure (Bi/BiCeO1...

Establishing appropriate metal-support interactions is imperative for acquiring efficient and corrosion-resistant catalysts for water splitting. Herein, the interaction mechanism between Ru nanoparticles and a series of titanium oxides, including TiO, Ti4 O7 and TiO2, designed via facile non-stoichiometric engineering is systematically studied. Ti4 O7, with the unique band structure, high conductivity and chemical stability, endows with ingenious metal-support interaction through interfacial Ti-O-Ru units, which stabilizes Ru species during OER and triggers hydrogen spillover to accelerate HER kinetics...

Efficient and durable electrocatalysts with sufficient active sites and high intrinsic activity are essential for advancing energy-saving hydrogen production technology. In this study, a Mott-Schottky heterojunction electrocatalyst with Ag nanoparticles in-situ grown on NiFe layered double hydroxides (NiFe-LDH)/NiFe2 O4 nanosheets (Ag@NiFe-LDH/NiFe2 O4 ) were designed and successfully synthesized through a hydrothermal process and subsequent spontaneous redox reaction. The in-situ growth of metallic Ag on semiconducting NiFe-LDH/NiFe2 O4 triggers a strong electron interaction across the Mott-Schottky interface, leading to a significant increase in both the intrinsic catalytic activity and the electrochemical active surface area of the heterojunction electrocatalyst...

Minimizing precious metal loading into electrocatalysts for water splitting is vital to promoting hydrogen energy technology toward practical applications. Low-content loading of precious-metal electrocatalysts is achieved by decorating precious metal nanostructures on co-electrocatalysts typically via surface confinement. Here, an electrocatalyst of ultralow-content Pt nanodots (0.71 wt%)/Ni3 Fe nanoparticles on reduced oxidation graphene (Pt/Ni3 Fe/rGO) is constructed for overall water splitting by pyrolyzing a single-source precursor PtCl6 3- guest-intercalated MgNiFe-layered double hydroxide (MgNiFe-LDH) host via a distinctive interlayer confinement...

Each year, millions of poultry succumb to highly pathogenic avian influenza A virus (AIV) and infectious bursal disease virus (IBDV) infections. Conventional vaccines based on inactivated or live-attenuated viruses are useful tools for disease prevention and control, yet, they often fall short in terms of safety, efficacy, and development times. Therefore, versatile vaccine platforms are crucial to protect poultry from emerging viral pathogens. Self-amplifying (replicon) RNA vaccines offer a well-defined and scalable option for the protection of both animals and humans...

Ensuring high catalytic activity and durability at low Ir usage is still a big challenge for the development of electrocatalysts towards oxygen evolution reaction (OER) in proton exchange membrane water electrolysis (PEMWE). Here, a rapid liquid-reduction combined with surface galvanic replacement strategy is reported to synthesize the sub 2 nm high-entropy alloy (HEA) nanoparticles featured with Ir-rich IrRuNiMo medium-entropy oxide shell (Ir-MEO) and a IrRuCoNiMo HEA core (HEA@Ir-MEO), which exhibits a low overpotential of 243 mV at 10 mA cm-2 and high mass activity (261...

Electrochemical activation usually accompanies in situ atom rearrangement forming new catalytic sites with higher activity due to reconstructed atomic clusters or amorphous phases with abundant dangling bonds, vacancies, and defects. By harnessing the pre-catalytic process of reconstruction, a multilevel structure of CuNi alloy nanoparticles encapsulated in N-doped carbon (CuNi nanoalloy@N/C) transforms into a highly active compound of Ni-doped CuO nanocluster supported on (N/O-C) co-doped C. Both the exposure of accessible active sites and the activity of individual active sites are greatly improved after the pre-catalytic reconstruction...

A high-temperature pyrolysis-controlled coordination reconstruction resulted in a single-Ni-atom structure with a Ni-N x -C structural unit ( x = N atom coordinated to Ni). Pyrolysis of Ni-phen@ZIF-8-RF at 700 °C resulted in NiNP-NC-700 with predominantly Ni nanoparticles. Upon elevating the pyrolysis temperature from 700 to 900 °C, a coordination reconstruction offers Ni-N x atomic sites in NiSA-NC-900. A combined investigation with X-ray absorption spectroscopy, X-ray photoelectron spectroscopy, and soft X-ray L3 -edge spectroscopy suggests the stabilization of low-valent Ni δ + (0 < δ < 2) in the Ni-N-C structural units...

The development of cost-effective, high-activity and stable catalysts to accelerate the sluggish kinetics of cathodic oxygen reduction/evolution reactions (ORR/OER) plays a critical part in commercialization application of rechargeable Zn-air batteries (RZABs). Herein, a multiscale nanoengineering strategy is developed to simultaneously stabilize Co-doped Fe nanoparticles originated from metal-organic framework-derived approach and atomic Fe/Co sites derived from metal nanoparticle-atomized way on N-doped hierarchically tubular porous carbon substrate...

Highly efficient electrocatalysts for water electrolysis are crucial to the widespread commercialization of the technology and an important step forward toward a sustainable energy future. In this study, an alternative method for boosting the electrocatalytic activity toward the oxygen evolution reaction (OER) of a well-known electrocatalyst (iridium) is presented. Iridium nanoparticles (2.1 ± 0.2 nm in diameter) functionalized with chiral molecules were found to markedly enhance the activity of the OER when compared to unfunctionalized and achiral functionalized iridium nanoparticles...

Developing high-performance bifunctional electrocatalysts towards the hydrogen evolution reaction/oxygen evolution reaction (HER/OER) holds great significance for efficient water splitting. This work presents a two-stage metal-organic thermal evaporation strategy for the fabrication of Ru-based catalysts (Ru/NF) through growing ruthenium (Ru)/ruthenium dioxide (RuO2 ) nanoparticles (NPs) on nickel foam (NF). The optimal Ru/NF shows remarkable performance in both the HER (26.1 mV) and the OER (235.4 mV) at 10 mA cm-2 in an alkaline medium...

Rational construction of efficient and robust bifunctional oxygen electrocatalysts is key but challenging for the widespread application of rechargeable zinc-air batteries (ZABs). Herein, bifunctional ligand Co metal-organic frameworks were first explored to fabricate a hybrid of heterostructured CoOx /Co nanoparticles anchored on a carbon substrate rich in CoNx sites (CoOx /Co@CoNC) via a one-step pyrolysis method. Such a unique heterostructure provides abundant CoNx and CoOx /Co active sites to drive oxygen reduction reaction (ORR) and oxygen evolution reaction (OER), respectively...

Exploiting effective, stable, and cost-efficient electrocatalysts for the water oxidation reaction is highly desirable for renewable energy conversion techniques. Constructional design and compositional manipulation are widely used approaches to efficaciously boost the electrocatalytic performance. Herein, we designed a NiFe-bimetallic sulfide/N-doped carbon composite via a two-step thermal treatment of Prussian blue analogues/cellulose nanofibers (PBA/CNFs) film. The NiFe-bimetallic sulfide/N-doped carbon composite displayed enhanced OER performance in an alkaline environment, with an overpotential of 282 mV at 10 mA cm-2 , a Tafel slope of 59...