Rone Aparecido De Grandis, Analu Rocha Costa, Carlos André Ferreira Moraes, Natália Zaneti Sampaio, Igor Henrique Cerqueira, Wellington Garcia Marques, Adriana Pereira Mundin Guedes, João Honorato de Araujo-Neto, Fernando Rogério Pavan, Felipe Cerqueira Demidoff, Chaquip Daher Netto, Alzir Azevedo Batista, Flávia Aparecida Resende
For the first time, we herein report on the syntheses of two new Ru(II)/bipyridine/phenanthroline complexes containing lapachol as ligand: complex (1), [Ru (bipy)2 (Lap)]PF6 and complex (2), [Ru(Lap)(phen)2 ]PF6 , where bipy = 2,2'-bipyridine and ph en = 1,10-phenanthroline; Lap = lapachol (2-hydroxy-3-(3-methylbut-2-en-1- yl)naphthalene-1,4-dione). The complexes were synthesized and characterized by elemental analyses, molar conductivity, mass spectrometry, ultraviolet-visible and infrared spectroscopies, nuclear magnetic resonance (1 H, 13 C), and single crystal X-ray diffraction, for complex (2)...
September 19, 2022: Journal of Inorganic Biochemistry