Yonglong Zheng, Xinyu Li, Liping Huang, Xiaoxin Li, Shenghao Yang, Qian Wang, Jiaxin Du, Yawen Wang, Weiqiang Ding, Bo Gao, Hongyu Chen
Under the control of chiral ligand glutathione and in the presence of hexadecyltrimethylammonium bromide, Au deposition on Au seeds is known to give chiral nanostructures. We have previously shown that the protruding chiral patterns, as opposed to flat facets, are likely caused by active surface growth, where nonuniform ligand coverage could be responsible for the focused growth at a few active sites. By pushing the limit of such a growth mode, here, we use decahedral seeds to prepare homochiral nanopropellers with intricate patterns of deep valleys and protruding ridges...
December 28, 2023: Journal of the American Chemical Society